Demospongic Acids Revisited
نویسندگان
چکیده
The well-known fatty acids with a Δ5,9 unsaturation system were designated for a long period as demospongic acids, taking into account that they originally occurred in marine Demospongia sponges. However, such acids have also been observed in various marine sources with a large range of chain-lengths (C(16)-C(32)) and from some terrestrial plants with short acyl chains (C(18)-C(19)). Finally, the Δ5,9 fatty acids appear to be a particular type of non-methylene-interrupted fatty acids (NMA FAs). This article reviews the occurrence of these particular fatty acids in marine and terrestrial organisms and shows the biosynthetic connections between Δ5,9 fatty acids and other NMI FAs.
منابع مشابه
Synthesis of the Demospongic Compounds, (6Z, 11Z)-Octadecadienoic Acid and (6Z, 11Z)-Eicosadienoic Acid
A stereoselective synthesis of (6Z, 11Z)-octadecadienoic acid (1) and (6Z, 11Z)-eicosadienoic acid (2) from easily accessible pentane-1,5-diol (3) is described. Thus, compound 3 on pyranylation and oxidation gave the aldehyde 5 which was converted to the acid 7 by Wittig reaction with a suitable phosphorane. Its depyranylation and oxidation furnished the key aldehyde 9 which upon Wittig reactio...
متن کاملLipids and Fatty Acids of Nudibranch Mollusks: Potential Sources of Bioactive Compounds
The molecular diversity of chemical compounds found in marine animals offers a good chance for the discovery of novel bioactive compounds of unique structures and diverse biological activities. Nudibranch mollusks, which are not protected by a shell and produce chemicals for various ecological uses, including defense against predators, have attracted great interest for their lipid composition. ...
متن کاملThe Holo-Transcriptome of a Calcified Early Branching Metazoan
Symbiotic interactions are widespread throughout the animal kingdom and are increasingly recognized as an important trait that can shape the evolution of a species. Sponges are widely understood to be the earliest branching clade of metazoans and often contain dense, diverse yet specific microbial communities which can constitute up to 50% of their biomass. These bacterial communities fulfill d...
متن کاملQUICKSELECT Revisited
We give an overview of the running time analysis of the random divide-and-conquer algorithm FIND or QUICKSELECT. The results concern moments, distribution of FIND’s running time, the limiting distribution, a stochastic bound and the key: a stochastic fixed point equation.
متن کاملThe function ring functors of pointfree topology revisited
This paper establishes two new connections between the familiar function ring functor ${mathfrak R}$ on the category ${bf CRFrm}$ of completely regular frames and the category {bf CR}${mathbf sigma}${bf Frm} of completely regular $sigma$-frames as well as their counterparts for the analogous functor ${mathfrak Z}$ on the category {bf ODFrm} of 0-dimensional frames, given by the integer-valued f...
متن کامل